Chemical Engineering Communications, Vol.153, 189-209, 1996
Pattern formation in solid film growth during CVD
This paper deals with the evolution of a gas-solid interface during growth of amorphous CVD films. The aim of the analysis is to show that a comprehensive gas-solid CVD model may simplify significantly under conditions of two limiting cases : kinetic and diffusion-limited growth. The linear stability behavior of the simplified model was found to be almost identical to that of the original and more comprehensive model. It was found that planar film growth was inherently stable under kinetically controlled deposition conditions, but under diffusion-limited conditions, planar film stability depended on the magnitude of the dimensionless group theta Pe, which represents a Damkohler number of deposition. Numerical solution of the simplified model showed that an increase in theta Pez adversely affected the uniformity of him deposition. Predicted morphological phenomena were found to be very similar to experimental observations (Viljoen, et al., 1994).
Keywords:CHEMICAL VAPOR-DEPOSITION;NON-LINEAR ANALYSIS;DENDRITIC SOLIDIFICATION;HYDRODYNAMIC INSTABILITY;LAMINAR FLAMES;STABILITY;FUNDAMENTALS;MORPHOLOGY