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Journal of Electroanalytical Chemistry, Vol.576, No.2, 353-362, 2005
Modelling diffusion to a disk electrode by fully explicit simulation
Fully explicit finite-difference simulation in oblate spheroidal coordinates is employed as a means of modelling concentrations near, and flux density at, an inlaid disk electrode under total diffusion control. The simulated current-versus-time relationship is found to concur excellently with those of dissimilar studies. (C) 2004 Elsevier B.V. All rights reserved.
Keywords:disk-electrode;microelectrodes;diffusion;oblate spheroidal coordinates;chronoamperometry;digital simulation