Journal of Physical Chemistry B, Vol.109, No.14, 6514-6519, 2005
Ultrafast to slow orientational dynamics of a homeotropically aligned nematic liquid crystal
The orientational dynamics of a homeotropically aligned nematic liquid crystal, 4 '-pentyl-4-biphenylcarbonitrile (5-CB), is studied over more than six decades of time (500 fs to 2 mu s) using optical heterodyne detected optical Kerr effect experiments. In contrast to the dynamics of nematogens in the isotropic phase, the data do not decay as a highly temperature-dependent exponential on the longest time scale, but rather, a temperature-independent power law spanning more than two decades of time, the final power law, is observed. On short time scales (similar to 3 ps to similar to 1 ns) another power law, the intermediate power law, is observed that is temperature dependent. The power law exponent of the correlation function associated with the intermediate power law displays a linear dependence on the change in the nematic order parameter with temperature. Between the intermediate power law and the final power law, there is a crossover region that displays an inflection point. The temperature-dependent orientational dynamics in the nematic phase are shown to be very different than those observed in the isotropic phase.