Thin Solid Films, Vol.479, No.1-2, 238-244, 2005
Photoluminescence characteristics of ZnGa2O4-xMx : Mn2+ (M= S, Se) thin film phosphors grown by pulsed laser ablation
Mn-doped ZnGa2O4-xMx (M=S, Se) thin film phosphors have been grown using a pulsed laser deposition technique at varying growth conditions. The structural characterization carried out on a series of ZnGa2O4-xMx:Mn2+ (M=S, Se) films grown on MgO (100) substrates using Zn-rich ceramic targets. Oxygen pressure was varied from 50 to 200 mTorr and substrate temperatures were varied from 500 to 700 degrees C. The lattice constants of the ZnGa2O4-xMx:Mn2+ (M=S, Se) thin film decrease with the substitution of sulfur and selenium for the oxygen in the ZnGa2O4. Measurements of photoluminescence (PL) properties of ZnGa2O4-xMx:Mn2+ (M=S, Se) thin films have indicated that MgO (100) is a promising substrate for the growth of high quality ZnGa2O4-xMx:Mn2+ (M=S, Se) thin films. In particular, a remarkable increase of green emission intensity was observed with ZnGa2O3.925Se0.075:Mn2+ and ZnGa2O3.925S0.075:Mn2+ films, whose brightness was increased by a factor of 3.1 and 1.4 in comparison with that of ZnGa2O4:Mn2+ films, respectively. Improved PL brightness with Se or S doping is suggested to result not only from improved crystallinity, but also from reduced internal reflections caused by rougher surfaces. The PL intensity and root mean square (rms) roughness behave similarly as a function of oxygen pressure. These phosphors maybe promising for application to the flat panel displays. (c) 2004 Elsevier B.V. All rights reserved.