전자선 및 자외선 경화형 방무코팅용 모노머의 합성 및 물성비교

조정대; 이재성; 김양배; 홍진후; Jung-Dae Cho; Jae-Sung Lee; Yang-Bae Kim; Jin-Who Hong

Journal of the Korean Industrial and Engineering Chemistry, Vol.16, No.3, 449-455, June, 2005

Export Citation

전자선 및 자외선 경화형 방무코팅용 모노머의 합성 및 물성비교

Synthesis and Comparison of EB- and UV-curable Monomers for Anti-fogging Coatings

조정대, 이재성¹, 김양배, 홍진후 ^{1, †}

(주)큐시스 광소재표면처리연구소
¹조선대학교 고분자공학과

Jung-Dae Cho, Jae-Sung Lee¹, Yang-Bae Kim, and Jin-Who Hong^{1, †}

Institute of Photonics & Surface Treatment, Q-Sys Co. Ltd., Gwangju 500-460, Korea
¹Department of Polymer Science & Engineering, Chosun University, Gwangju 501-759, Korea

E-mail:

초록

분자 내에 방무기능을 부여하기 위한 수산기와 전자선(EB) 및 자외선(UV) 경화가 가능한 아크릴레이트 관능기를 갖는 1관능성 및 4관능성 방무제 AF-1과 AF-2를 합성하여 EB 및 UV 경화시스템에 적용하였다. 합성된 AF-1과 AF-2를 UV 경화시스템에 적용하여 도막의 방무특성 및 경화물성을 측정한 결과, AF-1과 AF-2 함량을 5:17.5의 비로 함유한 배합이 표면과 내부경도, 내화학성 및 접착력이 저하되지 않으면서 김서림 방지 특성이 우수한 최적배합임을 알 수 있었다. 이 최적배합을 EB 경화시스템에 적용하였고, EB 및 UV 두 시스템에 의해 이루어진 코팅배합물을 PC sheet에 코팅하여 도막이 방무특성 및 경화물성을 비교 연구하였다. 그 결과 EB 및 UV에 의해 경화된 두 시스템 모두 우수한 방무특성을 나타냈으나 EB 시스템이 UV 시스템보다 더우수한 내부경도, 접착력 및 젖음성을 나타냄을 확인하였다.

Electron beam (EB) and ultraviolet (UV) curable monomers (AF-1 with mono functionality and AF-2 with tetra functionality) containing hydroxy and acrylate group for anti-fogging coating were synthesized and applied to EB and UV-curable coating systems. The synthesized reactive AF-1 and AF-2 monomers were first formulated into UV-curable system and the optimization of film properties for anti-fogging coating was investigated. The 5:17.5 ration for AF-1 and AF-2 was found to be the best optimized formulation for anti-fogging coating without destroying the other essential properties such as hardness, solvent resistance, and adhesion. The optimized formulation was applied to the EB-curable system, and EB and UV-curable systems were compared. The results demonstrated that both EB and UV-dured films coated on PC sheet showed excellent anti-fogging properties; however, the EB-cured film exhibited better hardness, adhesion, and water repellent properties than the UV-cured film.

Keywords:electron beam;ultraviolet;anti-fogging coating;FTIR-ATR spectroscopy;photo-DSC

[References]

Dorel D, Synthetic Polymers: Technology, Properties, Application, Chapman and Hall, London (1996)
Ebewele RO, Polymer science and technology, CRC Press, Boca Ranton, FL (2000)
Luning J, Yoon DY, Stohr J, J. Electron Spectrosc. Relat. Phenom., 121, 265 (2001)
Korea Patent 10-2002-0005450 (2003)
Korea Patent 10-2000-0051205 (2002)
Korea Patent 10-1999-0016788 (2000)
Davies WD, Hancock A, Hutchinson I, Williams B, Proceedings of RadTech North America, Baltimore, USA, 522 (2000)
Korea Patent 10-2003-0012206 (2003)
Korea Patent 10-1998-0027405 (2000)
Cho JD, Kim EO, Kim HK, Hong JW, Polym. Test, 21, 781 (2002)
Pyun HC, Nho YC, Polym.(Korea), 12(5), 389 (1988)
Nho Y, J. Korean Ind. Eng. Chem., 3(2), 341 (1992)

[Related Articles]

[1] Dorel D, Synthetic Polymers: Technology, Properties, Application, Chapman and Hall, London (1996)

[2] Ebewele RO, Polymer science and technology, CRC Press, Boca Ranton, FL (2000)

[3] Luning J, Yoon DY, Stohr J, J. Electron Spectrosc. Relat. Phenom., 121, 265 (2001)

[4] Korea Patent 10-2002-0005450 (2003)

[5] Korea Patent 10-2000-0051205 (2002)

[6] Korea Patent 10-1999-0016788 (2000)

[7] Davies WD, Hancock A, Hutchinson I, Williams B, Proceedings of RadTech North America, Baltimore, USA, 522 (2000)

[8] Korea Patent 10-2003-0012206 (2003)

[9] Korea Patent 10-1998-0027405 (2000)

[10] Cho JD, Kim EO, Kim HK, Hong JW, Polym. Test, 21, 781 (2002)

[11] Pyun HC, Nho YC, Polym.(Korea), 12(5), 389 (1988)

[12] Nho Y, J. Korean Ind. Eng. Chem., 3(2), 341 (1992)