Macromolecular Research, Vol.13, No.5, 441-445, October, 2005
Stress-Strain Behavior of the Electrospun Thermoplastic Polyurethane Elastomer Fiber Mats
E-mail:
Thermoplastic polyurethane elastomer (TPUe) fiber mats were successfully fabricated by electrospinning method. The TPUe fiber mats were subjected to a series of cycling tensile tests to determine the mechanical behavior. The electrospun TPUe fiber mats showed non-linear elastic and inelastic characteristics which may be due to slippage of crossed fiber (non-bonded or physical bonded structure) and breakage of the electrospun fibers at junctions (point-bonded or chemical bonding structure). The scanning electron microscopy (SEM) images demonstrated that the point-bonded structures of fiber mats played an important role in the load-bearing component as determined in loading-unloading component tests, which can be considered to have a force of restitution.
- Szycher M, Handbook of polyurethanes, CRC press LLC, New York (1999)
- Formhals A, US Patent 1,975,504 (1934)
- Reneker DH, Chun I, Nanotechnology, 7, 216 (1996)
- Deitzel JM, Kleinmeyer JD, Hirvonen JK, Tan NCB, Polymer, 42(19), 8163 (2001)
- Ohgo K, Zhao CH, Kobayashi M, Asakura T, Polymer, 44(3), 841 (2003)
- Lee KH, Kim HY, Khil MS, Ra YM, Lee DR, Polymer, 44(4), 1287 (2003)
- Ding B, Kim HY, Lee SC, Shao CL, Lee DR, Park SJ, Kwag GB, Choi KJ, J. Polym. Sci. B: Polym. Phys., 40(13), 1261 (2002)
- Shin YM, Hohman MM, Brenner MP, Rutledge GC, Polymer, 42(25), 9955 (2001)
- Hohman MM, Shin M, Rutledge G, Brenner MP, Phys. Fluids, 13, 2201 (2001)
- Hohman MM, Shin M, Rutledge G, Brenner MP, Phys. Fluids, 13, 2221 (2001)
- Feng JJ, Phys. Fluids, 14, 3912 (2002)
- Spivak AF, Dzenis YA, Appl. Phys. Lett., 73, 3067 (1998)
- Lee KH, Kim HY, La YM, Lee DR, Sung NH, J. Polym. Sci. B: Polym. Phys., 40(19), 2259 (2002)
- Deitzel JM, Kleinmeyer J, Harris D, Tan NCB, Polymer, 42(1), 261 (2001)
- Lee KH, Kim HY, Ryu YJ, Kim KW, Choi SW, J. Polym. Sci. B: Polym. Phys., 41(11), 1256 (2003)
- Pedicini A, Farris RJ, Polymer, 44(22), 6857 (2003)
- Laraba-Abbes F, Ienny P, Piques R, Polymer, 44(3), 821 (2003)
- Septanika EG, Ernst LJ, Mech. Mater., 30, 265 (1998)
- Johnson MA, Beatty MF, Int. J. Eng. Sci., 33, 223 (1995)
- Mullins LJ, Rubber Res. Inst. Malaya., 16, 275 (1947)