Poly(L-lactic acid) (PLLA) has poor heat stability above its glass transition temperature (T(g)similar to 60 degrees C). To improve its softing above T, PLLA was mixed with small amount of crosslinking agents and irradiated with various irradiation doses to introduce crosslinking between polymer chains. The most effective agent for radiation crosslinking was triallyl isocyanurate (TAIC). For melt-quenched PLLA, it was found that the most optimal conditions to introduce crosslinking were around 3% of TAIC and the irradiation dose of 50 kGy. The typically crosslinked PLLA showed very low crystallinity because of wide formation of molecular chain network that inhibited molecular motion for crystallization. Notable heat stability above T-g was given by annealing of PLLA samples. Enzymatic degradation of PLLA was retarded with introduction of crosslinks. (c) 2005 Elsevier Ltd. All rights reserved.