Cellulose nonwoven mats of submicron-sized fibers (150 nm-500 nm in diameter) were obtained by electrospinning cellulose solutions. A solvent system based on lithium chloride (LiCl) and N,N-dimethylacetamide (DMAc) was used, and the effects of W temperature of the collector, (ii) type of collector (aluminum mesh and cellulose filter media), and (iii) postspinning treatment, such as coagulation with water, on the morphology of electrospun fibers were investigated. The scanning electron microscopy (SEM) and X-ray diffraction studies of as-spun fibers at room temperature reveal that the morphology of cellulose fibers evolves with time due to moisture absorption and swelling caused by the residual salt and solvent. Although heating the collector greatly enhances the stability of the fiber morphology, the removal of salt by coagulation and DMAc by heating the collector was necessary for the fabrication of dry and stable cellulose fibers with limited moisture absorption and swelling. The presence and removal of the salt before and after coagulation have been identified by electron microprobe and X-ray diffraction studies. When cellulose filter media is used as a collector, dry and stable fibers were obtained without the coagulation step, and the resulting electrospun fibers exhibit good adhesion to the filter media. (c) 2005 Wiley Periodicals, Inc.