화학공학소재연구정보센터
Journal of Vacuum Science & Technology A, Vol.23, No.4, 911-916, 2005
Evaluation of silicon oxide cleaning using F-2/Ar remote plasma processing
In this study, chamber cleaning experiments using a F-2/Ar remote plasma generated from a toroidal-type remote plasma source were carried out in a plasma enhanced chemical vapor deposition (PECVD) system. The cleaning processes for the various silicon oxide layers, including PE-oxide (deposited by PECVD using SiH4 and N2O), O-3-TEOS oxide (deposited by thermal CVD using ozone and TEOS precursor), and BPSG (borophosphosilicate glass), were investigated by varying the various process parameters, such as the F-2 gas flow rate, the F-2/(F-2+Ar) flow ratio, and the cleaning temperature. The species emitted during cleaning were monitored by Fourier transformed infrared spectroscopy and residual gas analysis. Under the current experimental conditions, the cleaning rate of the BPSG was 4.1-5.0 and 3.9-7.3 times higher than that those of the PE-oxide and O-3-TEOS oxide layers, respectively, at room temperature and an F-2/(F-2 + Ar) flow ratio of 28.5%-83%. As the,cleaning temperature increased from 100 to 350 degrees C, the cleaning rates of the PE-oxide, O-3-TEOS oxide, and BPSG layers were increased by factors of 2.0-3.0, 1.5-2.2, and 3.0-3.4, respectively, at an F-2/(F-2+Ar) flow ratio of 28%-68%. The F-2/(F-2+Ar) flow ratio and cleaning temperature were found to be the most critical parameters involved in determining the cleaning rate of the various oxide layers. (c) 2005 American Vacuum Society.