A series of novel inorganic-organic hybrid positively charged membranes were prepared by coupling of 3-glycidoxypropyltrimethoxysilane (GPTMS) and mixed GPTMS/Ti(O-n-C4H9)(4) in n-butyl alcohol (BuOH) Solution at various temperatures and then followed quaternary amination with trimethyl amine (TMA). The synthesized membranes were characterized by IEC, streaming potential, pure water flux, FT-IR, TGA measurements as well as SEM observations. It was exhibited that anion exchange capacities (IECs) of the membranes decreased with increasing curing temperature within a range of (1.4-3.1) x 10(-2) mequiv. cm(-2) coated for one time and (3.5-4.6) x 10(-2) mequiv. cm(-2) coated for two times. The positive charge of the membranes was approved by these IEC values as well as FT-IR spectrum of step products and streaming potential values. The thermal stability was tested by TGA analysis and showed that the membranes doped with titanium could undergo a curing temperature up to 300 degrees C. Pure water flux showed that they decreased with increasing curing temperature, the composition of precursor and dip-coating times, respectively. SEM observations indicated that the membranes became thicker and denser with increasing content of titanium, but excessive Ti-content would decrease the stability of Si-O-Ti bonds in the membranes. (c) 2005 Elsevier B.V. All rights reserved.