A solid state C-13 NMR Study of hardened networks obtained by the reaction of blocked and non-blocked isocyanates (pMDI) With urea-formaldehyde (UF) resins in water showed different results according to the temperature of the reaction. At high temperature, in water, both a nonblocked or an emulsifiable, blocked isocyanate, appear to crosslink with UF resins through the formation both of traditional methylene bridges Connecting Urea to urea and of urethane bridges. The latter have been confirmed by C-13 NMR to form in water by reaction of the isocyanate -N=C=O group with them hydroxymethyl groups of the UF resin. At ambient temperature, UF/pMDI resins where the pMDI is a emulsifiable blocked isocyanate, do not appear to form urethanes to any great extent but rather to crosslink through the usual UF resin Urea to urea methylene bridges. Even in this case, When urethane bridges appear to be absent, evidence of crosslinking in water through reaction of the isocyanate with the -NH2 and -NH-amide of the UF resin has not been observed. (c) 2005 Wiley Perodicals, Inc.