화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Macromolecular Research, Vol.14, No.1, 81-86, February, 2006
Export Citation
Synthesis and Characterization of Poly(fluorenylenevinylene-terphenylenevinylene) Containing Phenyl Pendant Group
Yun-Hi Kim, Sung-Ouk Jung, Kwang-Hoi Lee, and Soon-Ki Kwon†
  • Department of Polymer Science & Engineering and Engineering Research Institute, Gyeongsang National University, Chinju 660-701, Korea
E-mail:
Poly(fluorenylenevinylene-terphenylenevinylene) containing phenyl pendant group was synthesized by Suzuki coupling reaction and characterized by 1H-NMR, 13C-NMR, and IR-spectrum. The weight average molecular weight (Mw) of the obtained polymer was 31,000 with a polydispersity index of 1.9. The polymer showed good solubility in common organic solvents, and the solution and film emitted blue emission ( λmax=460 nm) on irradiation with UV light. The ITO/PEDOT/polymer/Al device fabricated using the polymer as an emitting layer emitted blue light with a maximum peak around 460 nm. The maximum efficiency of the device was 0.011%.
Keywords:light-emitting diode;poly(fluorenylenevinylene-terphenylenevinylene);blue emission
  1. Yang Y, Heeger AJ, Nature, 372(6504), 344 (1994) 
  2. Strukelj M, Papadimitrakopoulos M, Miller F, Miller TM, Rotherberg LJ, Science, 270, 1969 (1995) 
  3. Andersson M, Yu G, Heeger AJ, Synth. Met., 85, 1275 (1997) 
  4. Choi CS, Kim IT, Lee SW, Lee HH, Lee YN, Jeon KS, Lee KH, Sung ND, Kil MJ, Lee YI, Macromol. Res., 12(3), 322 (2004)
  5. Kim DY, Cho HN, Kim CY, Prog. Polym. Sci, 25, 1089 (2000) 
  6. Dai L, Winkler B, Dong L, Tong L, Mau AWH, Adv. Mater., 13, 915 (2001) 
  7. Pei QB, Yang Y, J. Am. Chem. Soc., 118(31), 7416 (1996) 
  8. Yang Y, Pei Q, J. Appl. Phys., 81, 3294 (1997) 
  9. Klaerner G, Miller RD, Macromolecules, 31(6), 2007 (1998) 
  10. Zheng M, Ding LM, Lin ZQ, Karasz FE, Macromolecules, 35(27), 9939 (2002) 
  11. Janietz S, Bradley DDC, Grell M, Giebeler C, Inbasekaran M, Woo EP, Appl. Phys. Lett., 74, 3084 (1999) 
  12. Roncali J, J. Chem. Rev., 92, 71 (1992)
  13. Grem G, Leditzky G, Ullrich B, Leising G, Adv. Mater., 4, 36 (1992) 
  14. An BK, Kim YH, Shin DC, Park SY, Yu HS, Kwon SK, Macromolecules, 34(12), 3993 (2001) 
  15. Kim YH, Shin DC, Kwon SK, Lee JH, J. Mater. Chem., 12, 1280 (2002) 
  16. Kim YH, Ahn JH, Shin DC, Kim HS, Kwon SK, Opt. Mater., 21, 175 (2002)
  17. Kim YH, Ahn JH, Shin DC, Kim JH, Park YW, Choi DS, Kim YK, Kwon SK, Bull. Korean Chem. Soc., 22, 1181 (2001)
  18. Kim YH, Ahn JH, Shin DC, Kwon SK, Polymer, 45(8), 2525 (2004) 
  19. Kim YH, Shin DC, Kim HS, Kwon SK, Polymer (2005)
  20. Kim YH, Park JC, Kang HJ, Park JW, Kim HS, Kim JH, Kwon SK, Macromol. Res., 13(5), 403 (2005)
  21. Kim YH, Kwon SK, Yoo DS, Rubner MF, Wrighton MS, Chem. Mater., 9, 2699 (1997) 
  22. Cho HN, Kim DY, Kim YC, Kim JY, Lee JY, Kim CY, Adv. Mater., 9, 326 (1997) 
  23. Ng S, Lu H, Chan HSO, Fujii A, Laga T, Yoshino K, Adv. Mater., 12, 1122 (2000) 
  24. Tao X, Zhang Y, Wada T, Sasabe H, Suzuki H, Watanabe T, Miyata S, Adv. Mater., 10, 226 (1998) 
  25. Cimrova V, Neher D, Remmers M, Kimnek I, Adv. Mater., 10, 676 (1998)