The feasibility of a carbon dioxide disposal method based on combining carbon dioxide chemically with silicate rocks was tested in this experiment. The process uses a stirred batch reactor, in which supercritical carbon dioxide is absorbed into a rock slurry to cause dissolution of the mineral and precipitation of calcium carbonate. Wollastonite (CaSiO3) was chosen in a systematic study because it had the highest conversion among the rocks investigated in a preliminary test. The effects of operating variables-including reaction time, reaction pressure, the particle size of wollastonite, reaction temperature, and solution composition-on the conversion of wollastonite were investigated, and a reaction mechanism was proposed to explain these effects. The conversion was determined by means of thermogravimetric analysis. A high conversion of 90% was achieved by using a solution composed of I M NaHCO3 to prepare the wollastonite slurry when the carbonation reaction was operated at 8.6 MPa and 383 K for 6 h. (c) 2005 American Institute of Chemical Engineers.