In this study, computer modeling and simulation works were performed to obtain nearly pure toluene prod-uct from toluene containing non-aromatic compounds using sulfolane as a solvent through an extractive distillation pro-cess. NRTL liquid activity coefficient model was adopted for phase equilibrium calculations and Aspen Plus release12.1, a commercial process simulator, was used to simulate the extractive distillation process. In this study, it was con-cluded that the toluene product with a purity of 99.8 percent by weight and a recovery of 99.65 percent was obtainedthrough an extractive distillation process.