The unimolecular dissociation dynamics of aluminum clusters following collision with either a rare gas atom or a surface is investigated by classical trajectory simulations with model potentials. Two conformers of Al-6 with very distinct shapes, i.e., the spherical O-h and planar C-2h clusters, are considered in this work. The initial vibrational energy and angular momentum distributions resulting from collision, as well as the energy and angular momentum resolved lifetime distributions, of excited clusters were determined for both collision-induced dissociation (CID) and surface-induced dissociation (SID) processes. The partitioning of excitation energy acquired upon collision was found to depend on the excitation mechanism (CID or SID), as well as on the cluster molecular shape, especially in the case of CID. For both types of processes, the energy and angular momentum resolved excited cluster lifetime distributions were found to decay exponentially, in agreement with statistical theories of chemical reactions, suggesting intrinsic Rice-Ramsperger-Kassel-Marcus (RRKM) behavior. Moreover, the simulated microcanonical rate constants determined from the cluster lifetime distributions are in good agreement with the predictions of the orbiting transition state model of phase space theory (OTS/PST), which further supports the statistical character of cluster CID and SID. Thus, in the CID and SID of highly fluxional systems such as aluminum clusters, the rate of intramolecular vibrational energy redistribution (IVR) is much faster than the dissociation rate, which validates one of the key assumptions, i.e., post-collision statistical behavior, underlying the models that are routinely used to determine cluster binding energies from experimental CID/SID cross sections.