화학공학소재연구정보센터
Journal of Rheology, Vol.49, No.6, 1303-1316, 2005
Aging properties of semidilute aqueous solutions of polyethylene oxide seeded with silica nanoparticles
Rheological properties of semidilute aqueous solutions of polyethylene oxide (PEO) seeded with silica nanoparticles are studied as a function of aging time. The viscosity, dynamic moduli, and extensional properties of solutions of 0.5% PEO of 4 million g/mol molecular weight seeded with 10-20 nm silica particles in concentrations of 1%, 2%, and 3% by weight are greatly enhanced by the nanoparticles. The aforementioned properties were measured every week over a period of up to 18 weeks. The degradation of theological properties with aging time in this period is greatly reduced and, in some cases is completely suppressed, by nanoparticles. The evolution of properties of these nanosolutions is not perfectly understood but is possibly determined in a resolution of the competing effects of adsorption of PEO onto the silica with cleavage of the polymers due to oxidation and other effects at work in static samples. (c) 2005 The Society of Rheology.