Combustion Science and Technology, Vol.178, No.5, 953-973, 2006
A global NOX submodel for pulverized coal flames at elevated pressures
This study formulates a global NOX submodel for deployment in CFD simulations from a database on flames of three diverse coals at pressures to 3.0MPa for broad ranges of stoichiometric ratio ( S. R.). A new reaction scheme was formulated from a sensitivity analysis of simulations based on detailed reaction mechanisms for all tests. It shares many elements in common with commercial submodels, yet it correctly predicts that ( 1) less coal- N is converted into NO; and ( 2) HCN persists to higher S. R. for progressively higher pressures. Explicit dependences on O-2 concentrations are responsible for the first feature, because the variations in O-2 concentrations mimic the ways that the oxyhydroxyl radical pool shrinks at progressively higher pressures, which shifts HCN conversion toward N-2 production. The second feature was depicted by resolving the intermediate products of HCN decomposition in the global scheme. Discrepancies surfaced when the new submodel was applied to different coals without re- adjusting rate parameters, which probably reflects a generic limitation of global NOX production submodels for coal combustion.