In order to enhance the ionic conductivity of polyethylene oxide (PEO)-KOH based alkaline polymer electrolytes, three types of nanopowders, i.e., TiO2, beta-Al2O3 and SiO2 were added to PEO-KOH complex, respectively, and the corresponding composite alkaline polymer electrolytes were prepared. The experimental results showed that the prepared polymer electrolytes exhibited higher ionic conductivities at room temperature, typically 10(-3) S cm(-1) as measured by ac impedance method, and good electrochemical stability. The electrochemical stability window of ca. 1.6 V was determined by cyclic voltammetry with stainless steel blocking electrodes. The influence of the film composition such as KOH, H2O and nano-additives on ion conductivity was investigated and explained. The temperature dependence of conductivity was also determined. In addition, polyvinyl alcohol (PVA)-sodium carboxymethyl cellulose (CMC)-KOH alkaline polymer electrolytes were obtained using solvent casting method. The properties of the polymer electrolytes were characterized by ac impedance, cyclic voltammetry and differential thermal analysis methods. The ionic conductivity of the prepared PVA-CMC-KOH-H2O electrolytes can reach the order of 10(-2) S cm(-1). The effect of CMC addition on the alkaline polymer electrolytes was also explained. The experimental results demonstrated that the PVA-CMC-KOH-H2O polymer electrolyte could be used in Ni/MH battery. (c) 2005 Elsevier Ltd. All rights reserved.