Journal of Materials Science, Vol.41, No.2, 377-382, 2006
Thermally stimulated discharge current and DC resistivity of ethylene propylene rubber with various Pb concentrations
DC resistivity of extruded ethylene propylene rubber (EPR) samples with various Pb concentration have been measured under wet conditions as a function of electrical field at selected temperatures in a range from 20 to 100 degrees C. The temperature and electrical field coefficients of resistivity have been calculated. Thermally stimulated discharge current (TSDC) has also been measured and a broad positive peak has been observed for three EPR samples. It has been found that the resistivity of EPR is not sensitive to the Pb concentration within the range of 0 to 5 parts per hundred base resin (phr). The results show that the resistivity of EPR varies non-linearly with both temperature and electrical field. The temperature coefficient of resistivity alpha of EPR has been measured to be similar to 0.1 K-1 for all the samples with various Pb concentration. The electrical field coefficient of resistivity beta of EPR at room temperature is small and increases with temperature. Increasing Pb content increases slightly the electrical field coefficient beta of resistivity. Based on a space charge limited conduction model, the trap depth of EPR has been estimated. TSDC measurements indicate that doping with Pb increases both the density of charge carriers and the number of deep traps simultaneously. The broad TSDC peak reveals that there must be a distribution rather than just a single value of the trap depth. (c) 2006 Springer Science + Business Media, Inc.