화학공학소재연구정보센터
Journal of Physical Chemistry A, Vol.110, No.10, 3364-3376, 2006
Double-channel contact recombination of radical pairs subjected to spin conversion via the Delta g mechanism
The contact recombination from both singlet and triplet states of a radical pair is studied assuming that the spin conversion is carried out by the fast transversal relaxation and Ag mechanism. The alternative HFI mechanism is neglected as being much weaker in rather large magnetic fields. The magnetic-field-dependent quantum yields of the singlet and triplet recombination products, as well as of the free radical production, are calculated for any initial spin state and arbitrary separation of radicals in a pair. The magnetic field effect is traced and its diffusional (viscosity) dependence is specified.