Journal of Polymer Science Part B: Polymer Physics, Vol.44, No.8, 1188-1198, 2006
The influence of thermoelastomers on the crystallization Behavior of isotactic polypropylene under
The crystallization behaviors of isotactic polypropylene (iPP) and its blends with thermoelastomers have been investigated with in situ X-ray scattering and optic microscopy. At quiescent condition, the crystallization kinetics of iPP is not affected by the presence of elastomers; while determined by the viscosity, the differences are observed on sheared samples. With a fixed shear strain, the crystallization rate increases with increasing the shear rate. The fraction of oriented lamellar crystals in blends is higher than that in pure iPP sample, while the percentage of beta phase is reduced by the presence of the elastomers. On the basis of experimental results, no direct correlation among the fraction of oriented lamellae, the percentage of beta phase, and growth rate can be deduced. The evolution of the fraction of oriented lamellae supports that shear field promotes nucleation rather than growth process. Shear flow induces the formation of nuclei not only with preferring orientation but also with random orientation. The total density of nuclei, which determines the crystallization kinetics, does not control the ratio between nuclei with and without preferring orientation, which determines the fraction of oriented lamellae. (c) 2006 Wiley Periodicals, Inc.