Characterization and Formation of Phospholipid Nanoemulsion Coatings onMg-Modified Sericite Surface

Jeong Ho Chang; Min Ae Cho; Hong Ha Son; Cheon Koo Lee; Myung Seok Yoon; Hyung Hwan Cho; Dong Sung Seo; Kyung Ja Kim

Journal of Industrial and Engineering Chemistry, Vol.12, No.4, 635-638, July, 2006

Jeong Ho Chang^†, Min Ae Cho, Hong Ha Son^{1, †}, Cheon Koo Lee¹, Myung Seok Yoon¹, Hyung Hwan Cho², Dong Sung Seo², and Kyung Ja Kim

Korea Institute of Ceramic Engineering and Technology, Seoul 153-801, Korea
¹Cosmetic R&D Center, LG Household &Health Care Ltd., Taejeon 305-343, Korea
²R&D Center, Chemland, Pyengtaek, Gyenggi 451-851, Korea

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This paper describes the formation of phospholipid vesicles on an inorganic sericite surface, which were characterized by electron microscopy (FE-SEM, TEM) and evaluated qualitatively by XPS as a function of the etching time. The vesicle mobility on the surface was restrained through a chelation effect using magnesium cations; the degree of stabilization demonstrated at various concentrations of the magnesium cation showed that it had a much more pronounced influence on the lipid deposition process. Moreover, the Mg cations play an important role during the attaching of the phospholipids; the optimum concentration was 7mM.

Keywords:phospholipids;nanoemulsion;sericite;coating;XPS

[References]

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Radler J, Strey H, Sackmann E, Langmuir, 11(11), 4539 (1995)
Zhdanov VP, Keller CA, Glasmastar K, Kasemo B, J. Chem. Phys., 112(2), 900 (2000)
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Starr TE, Thompson NL, Langmuir, 16(26), 10301 (2000)
Penfold J, Staples E, Tucker I, Langmuir, 18(8), 2967 (2002)
Puu G, Gustafson I, Biochem. Biophys. Acta, 1327, 149 (1997)
Reviakine I, Simon A, Brisson A, Langmuir, 16(4), 1473 (2000)
Feigenson GW, Biochemistry, 28, 1270 (1989)
Hector RF, DeSantiago GS, Am. J. Physiol., 266, 1112 (1994)
Stanfield PR, Davies NW, Shelton PA, Khan IA, Brammar WJ, Standenn NB, Colney EC, J. Physol., 475, 1 (1994)
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Wisdom DM, Singh J, Domschke W, Stoll R, Mooren FC, J. Phys. Chem., 490, 485 (1995)
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[1] Watts TH, Brian AA, Kappler JW, Marreck PH, McConnell M, Proc. Nati. Acad. Sci. USA, 81, 7564 (1984)

[2] Aurora TS, Li W, Cummins HZ, Haines TH, Biochem. Biophys. Acta, 820, 250 (1985)

[3] Kang KC, Lee CI, Pyo HB, Jeong NH, J. Ind. Eng. Chem., 11(6), 847 (2005)

[4] Lee SJ, Jeong NH, Kim MS, J. Ind. Eng. Chem., 11(2), 248 (2005)

[5] Tero R, Takazawa M, Li YJ, Yamazaki M, Urisu T, Appl. Surf. Sci., 238, 218 (2004)

[6] Richter RP, Brisson AR, Biophys. J., 88, 3422 (2005)

[7] Hautala JT, Wiedmer SK, Riekkola ML, Electrophoresis, 26, 176 (2005)

[8] Cremer PS, Boxer SG, J. Phys. Chem. B, 103(13), 2554 (1999)

[9] Benes M, Billy D, Benda A, Speijer H, Hof M, Hermens WT, Langmuir, 20(23), 10129 (2004)

[10] Keller CA, Glasmaster K, Zhdanov VP, Kasemo B, Phys. Rev. Lett., 84, 5443 (2000)

[11] Jass J, Tjarnhage T, Puu G, Biophys. J., 79, 3153 (2000)

[12] Johnson JM, Taekijp H, Chu S, Boxer SG, Biophys. J., 83, 3371 (2002)

[13] Radler J, Strey H, Sackmann E, Langmuir, 11(11), 4539 (1995)

[14] Zhdanov VP, Keller CA, Glasmastar K, Kasemo B, J. Chem. Phys., 112(2), 900 (2000)

[15] Richter RP, Brisson A, Langmuir, 20(11), 4609 (2004)

[16] Zhdanov VP, Kasemo B, Langmuir, 17(12), 3518 (2001)

[17] Starr TE, Thompson NL, Langmuir, 16(26), 10301 (2000)

[18] Penfold J, Staples E, Tucker I, Langmuir, 18(8), 2967 (2002)

[19] Puu G, Gustafson I, Biochem. Biophys. Acta, 1327, 149 (1997)

[20] Reviakine I, Simon A, Brisson A, Langmuir, 16(4), 1473 (2000)

[21] Feigenson GW, Biochemistry, 28, 1270 (1989)

[22] Hector RF, DeSantiago GS, Am. J. Physiol., 266, 1112 (1994)

[23] Stanfield PR, Davies NW, Shelton PA, Khan IA, Brammar WJ, Standenn NB, Colney EC, J. Physol., 475, 1 (1994)

[24] Lamb GD, Stephenson DG, J. Physiol., 478, 331 (1994)

[25] Wisdom DM, Singh J, Domschke W, Stoll R, Mooren FC, J. Phys. Chem., 490, 485 (1995)

[26] Yilmaz E, Borchert H, Eur. J. Pharm. Biopharm., 60, 91 (2005)

[27] Danino D, Gupta R, Satyavolu J, Talmon Y, J. Colloid Interface Sci., 249(1), 180 (2002)

[28] Waninge R, Nylander T, Paulsson M, Bergenstahl B, Colloids Surf. B: Biointerfaces, 31, 257 (2003)