Excess molar enthalpies of dimethyl carbonate and (butanol isomers and 1-pentanol) at T = (298.15, 313.15, and 328.15) K and p = (0.1, 1.0, and 10.0) MPa

Yan WD; Peng B; Dong H; Zhang R; Li SY

Journal of Chemical Thermodynamics, Vol.38, No.5, 520-525, 2006

DOI10.1016/j.jct.2005.07.011 Export Citation

Excess molar enthalpies of dimethyl carbonate and (butanol isomers and 1-pentanol) at T = (298.15, 313.15, and 328.15) K and p = (0.1, 1.0, and 10.0) MPa

Yan WD, Peng B, Dong H, Zhang R, Li SY

A high-pressure flow-mixing isothermal microcalorimeter is used to determine the excess molar enthalpies of four binary for dimethyl carbonate and (butanol isomers and 1-pentanol) at T = (298.15, 313.15, and 328.15) K and p = (0.1, 1.0, 10.0) MPa. The smooth values calculated by Redlich-Kister equation of H-m(E) are also compared with the experimental results. (C) 2005 Elsevier Ltd. All rights reserved.

Keywords:dimethyl carbonate;1-butanol;2-butanol;2-methyl-2-propanol;1-pentanol;excess molar enthalpies