mu(1,1)-azide-bridged ferromagnetic Mn-III dimer with slow relaxation of magnetization

Ge CH; Cui AL; Ni ZH; Jiang YB; Zhang LF; Ribas J; Kou HZ

Inorganic Chemistry, Vol.45, No.13, 4883-4885, 2006

Ge CH, Cui AL, Ni ZH, Jiang YB, Zhang LF, Ribas J, Kou HZ

A new end-on azide-bridged dimeric Mn-III complex has been synthesized by using the tridentate N-isonicotinamidosalicylaidimine ligand. Magnetic studies show that the complex has a high-spin ground state of S = 4 and is ac out-of-phase frequency-dependent.