The axially substituted complex chloro indium(III) 2-tetrabromo-3-tetra-(3,5-di-tert-butylphenyloxy)naphthalocyanine [Br-4(tBu(2)PhO)(4)NcInCl (1); MW = 1996] has been synthesized for the first time, and its nonlinear transmission properties have been evaluated with the Z-scan technique in both open and closed aperture configurations at 532 nm for nanosecond pulsed radiation. The tetrabrominated complex 1 displayed a larger positive nonlinear absorption coefficient when compared to an analogous nonbrominated naphthalocyanine [(tBu(2)PhO)(8)NcInCl (2); MW = 2498]. The effect of the four Br atoms on the nonlinear optical behavior of 1 is evaluated, discussed, and compared with the nonlinear optical behavior of 2. It is shown that the bromination of the naphthalocyanine ring considerably improves the limiting properties of such a system when high-intensity radiations are produced by nanosecond laser pulses at 532 nm.