화학공학소재연구정보센터
Journal of Polymer Science Part B: Polymer Physics, Vol.44, No.13, 1853-1862, 2006
The use of Flory-Huggins parameters as a measure of interactions in polymer-filler systems
Any quantitative information on the strength of interactions between inorganic filler and polymer is substantial for the future application of the composite. The magnitude of adhesion of two phases may be deduced from results collected by various experimental techniques. Polyether-urethane/modified carbonate-silicate fillers systems containing different amount of filler (5, 10, and 20 wt %) were the materials investigated. We propose to express the magnitude of modified filler/polymer interactions by Flory-Huggins chi(23) parameter. It may be deduced from the results collected by inverse gas chromatographic (IGC) experiment. We have also tried to explain the influence of the solvent on values of the evaluated parameters and to check the usefulness of some of presented methods to minimize AZ effect. (c) 2006 Wiley Periodicals, Inc.