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Journal of Chemical Technology and Biotechnology, Vol.81, No.8, 1441-1446, 2006
The analysis of solvation in ionic liquids and organic solvents using the Abraham linear free energy relationship
The contentions made in an earlier paper [J Chem Technol Biotechnol 80: 133-137 (200S)] that the coefficients of the Abraham solvation equation do not provide meaningful information on the molecular properties of ionic liquid solvents is refuted. The objections noted in the earlier paper disappear when the solvation equation model is correctly applied to the experimental data. It is further shown that the coefficients of the Abraham solvation equations can be used to characterize ionic liquids and can be used to select solvents for the solubility of gaseous solutes. (c) 2006 Society of Chemical Industry.
Keywords:linear free energy relationship (LFER);solvation equations;ionic liquids;principal component analysis