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Separation Science and Technology, Vol.41, No.11, 2629-2634, 2006
Liquidus curves of NH4NO3 (aq) calculated from the modified adsorption isotherm model for aqueous electrolytes
The Stokes-Robinson modification of the Brunauer-Emmett-Teller (BET) adsorption isotherm is used to calculate the liquidus curve of NaNO3 (aq) including the eutectic point and metastable phases. The method described here represents a simplified approach to predict the liquidus curves with sparse information and considers the presence of several crystalline solid phases of NH4NO3 .
Keywords:activity coefficients;aqueous electrolyte;Brunauer-Emmett-Teller (BET);absorption isotherm;eutectic