Electrochimica Acta, Vol.51, No.25, 5334-5340, 2006
Dendrite short-circuit and fuse effect on Li/polymer/Li cells
We report on experimental and theoretical studies of dendritic growth in Li/polymer/Li symmetric cells. Potential evolution with time, impedance and in situ microscopy experiments enable to characterise the onset and evolution of dendrites. In particular we observe that dendrites may bum when a high enough current goes through them, a thermo-fusible effect predicted in a previous paper and confirmed by SEM experiments. We present a calculation that gives a quantitative description of this effect: our results enable to understand a series of experimental data published in the literature concerning impedance variations observed while cycling lithium-polymer cells. (c) 2006 Elsevier Ltd. All rights reserved.
Keywords:lithium-polymer battery;lithium dendrite;thermo-fusible effect;impedance spectroscopy;in situ microscopy