Ni + Mo + Si coatings were obtained by nickel deposition from a bath containing suspension of molybdenum and silicon powders. These coatings were obtained in galvanostatic conditions, at the current density of j(dep) = - 0.100 A cm(-2). For determination of the influence of phase composition and surface morphology of obtained coatings on changes of corrosion resistance, these coatings were modified in argon atmosphere by thermal treatment at the temperature of 1100 degrees C during I h. A scanning electron microscope was used for surface morphology characterization of the coatings. Chemical composition of obtained coatings was determined by X-ray fluorescence spectroscopy method. Phase composition investigations were conducted by X-ray diffraction method. It was found that the obtained coatings are composed of three phase structures, i.e., nickel, molybdenum and silicon. Phase composition for the Ni + Mo + Si coatings after thermal treatment is markedly different. The main peaks corresponding to the Ni and Mo coexist with the new ones corresponding to new phases: Mo5Si3, NiSi, Mo2Ni3Si and Ni6Mo6C1.06. Electrochemical corrosion resistance investigations were carried out in the 5 M KOH, using potentiodynamic and electrochemical impedance spectroscopy methods. On the basis of these investigations it was found that Ni + Mo + Si coatings after thermal treatment are more resistant in alkaline solution than Ni + Mo + Si as-deposited coatings. The reason of this is presence of silicides in the coatings. (c) 2006 Elsevier Ltd. All rights reserved.