화학공학소재연구정보센터
Journal of Chemical Thermodynamics, Vol.38, No.9, 1100-1104, 2006
Densities, excess molar volumes, and refractive indices of 1,1,2,2-tetrabromoethane and 1-alkanols binary mixtures
Densities, excess molar volumes, refractive indices, and changes in refractive index on mixing for (1, 1,2,2-tetrabromoethane + 1-pentanol, or 1-hexanol, or 1-heptanol, or 1-octanol, or 1-decanol) have been determined at T= 293.15 K and at T= 303.15 K. The excess molar volumes and changes in refractive index have been fitted to Redlich-Kister polynomials. The effect of the chain length of the 1-alkanol on the excess molar volume and the change in the refractive index of its mixtures with 1, 1,2,2-tetrabromoethane are discussed. In addition, the refractive indices are compared with calculated values using mixing rules proposed by several authors, and a good agreement is obtained. (c) 2005 Elsevier Ltd. All rights reserved.