화학공학소재연구정보센터
Journal of Power Sources, Vol.159, No.2, 1084-1088, 2006
New borohydride fuel cell with multiwalled carbon nanotubes as anode: A step towards increasing the power output
A borohydride fuel cell has been constructed using a platinized multimalled carbon nanotube (MWCNT) anode and an air cathode having an anionic exchange membrane separating the anode and cathode. The MWCNT was functionalized with carboxylic acid under nitric acid reflux. Platinum metal was subsequently incorporated into it by galvanostatic deposition. The platinized functionalized MWCNT was characterized by thermogravimetric analysis, Fourier transform infrared spectrum, scanning electron microscope and. X-ray diffraction. The fuel cell produced a voltage of 0.95 V at low currents and a maximum power density of 44mWcm(-2) at room temperature in 10% sodium borohydride in a 4 M sodium hydroxide medium. Another borohydride fuel cell under identical conditions using carbon as the anode produced a cell voltage of 0.90 V and power density of about 20 mW cm(-2). The improved performance of the MWCNT is attributed to the higher effective surface area and catalytic activity. (c) 2006 Elsevier B.V. All rights reserved.