Dispersion and separation of small-diameter single-walled carbon nanotubes

Maeda Y; Kanda M; Hashimoto M; Hasegawa T; Kimura S; Lian YF; Wakahara T; Akasaka T; Kazaoui S; Minami N; Okazaki T; Hayamizu Y; Hata K; Lu J; Nagase S

Journal of the American Chemical Society, Vol.128, No.37, 12239-12242, 2006

Maeda Y, Kanda M, Hashimoto M, Hasegawa T, Kimura S, Lian YF, Wakahara T, Akasaka T, Kazaoui S, Minami N, Okazaki T, Hayamizu Y, Hata K, Lu J, Nagase S

The dispersion of small-diameter single-walled carbon nanotubes (SWNTs) produced by the CoMoCAT method in tetrahydrofuran (THF) with the use of amine was studied. The absorption, photoluminescence, and Raman spectroscopies showed that the dispersion and centrifugation process leads to an effective separation of metallic SWNTs from semiconducting SWNTs. Since this method is simple and convenient, it is highly applicable to an industrial utilization for widespread applications of SWNTs.