Journal of Chemical Thermodynamics, Vol.38, No.10, 1172-1185, 2006
Viscosity, density, and speed of sound of methylcyclopentane with primary and secondary alcohols at T = (293.15, 298.15, and 303.15) K
Viscosities, densities, and speed of sound have been measured over the whole composition range for (methylcyclopentane with ethanol, 1-propanol, 1-butanol, 2-propanol, 2-butanol, and 2-pentanol) at T = (293.15, 298.15, and 303.15) K and atmospheric pressure along with the properties of the pure components. Excess molar volumes, isentropic compressibility, deviations in isentropic compressibility, and viscosity deviations for the binary systems at the above-mentioned temperatures were calculated and fitted to Redlich-Kister equation to determine the fitting parameters and the root-mean square deviations. UNIQUAC equation was used to correlate the experimental data. Dynamic viscosities of the binary mixtures have been predicted using UNIFAC-VISCO and ASOG-VISCO methods. (c) 2006 Elsevier Ltd. All rights reserved.
Keywords:density;methyl cyclopentane;ethanol;1-propanol;1-butanol;2-propanol;2-butanol;2-pentanol;UNIFAC-VISCO;ASOG-VISCO