Chemical Reviews, Vol.96, No.1, 505-522, 1996
Total Syntheses of Pumiliotoxin-A and Allopumiliotoxin Alkaloids - Interplay of Pharmacologically Active Natural-Products and New Synthetic Methods and Strategies
Keywords:ION-VINYLSILANE CYCLIZATIONS;ENANTIOSELECTIVE TOTAL SYNTHESIS;FORMAL TOTAL SYNTHESIS;IMINIUM ION;SODIUM-CHANNEL;A ALKALOIDS;STEREOCONTROLLED SYNTHESIS;ORGANOMETALLIC COMPOUNDS;ELECTROPHILIC ADDITION;ASYMMETRIC-SYNTHESIS