Korea-Australia Rheology Journal, Vol.18, No.4, 183-189, December, 2006
Emulsion rheology and properties of polymerized high internal phase emulsions
E-mail:
High internal phase emulsions are highly concentrated emulsion systems consisting of a large volume of dispersed phase above 0.74. The rheological properties of high internal phase water-in-oil emulsions were measured conducting steady shear, oscillatory shear and creep/recovery experiments. It was found that the yield stress is inversely proportional to the drop size with the exponent of values between 1 and 2. Since the oil phase contains monomeric species, microcellular foams can easily be prepared from high internal phase emulsions. In this study, the microcellular foams combining a couple of thickeners into the conventional formulation of styrene and water system were investigated to understand the effect of viscosity ratio on cell size. Cell size variation on thickener concentration could be explained by a dimensional analysis between the capillary number and the viscosity ratio. Compression properties of foam are important end use properties in many practical applications. Crush strength and Young's modulus of microcellular foams polymerized from high internal phase emulsions were measured and compared from compression tests. Of the foams tested in this study, the foam prepared from the organoclay having reactive group as an oil phase thickener showed outstanding compression properties.
Keywords:high internal phase emulsion;rheological properties;thickener;cell size;microcellular foam;compression properties
- Babak VG, Langenfeld A, Fa N, Stebe MJ, Prog. Colloid Polym. Sci., 118, 216 (2001)
- Barby D, Haq Z, Low density porous cross-linked polymeric materials and their preparation and use as carriers for included liquids, European Patent 0,060,138 (1982)
- BHUMGARA Z, Filtr. Sep., 32(3), 245 (1995)
- Bourne JR, Baldyga J, Chem. Eng. Sci., 49(7), 1077 (1994)
- Choi JS, Chun BC, Lee SJ, Macromol. Res., 11(2), 104 (2003)
- Duke JR, Hoisington MA, Langlois DA, Benicewicz BC, Polymer, 39(18), 4369 (1998)
- Grace HP, Chem. Eng. Commun., 14, 225 (1982)
- Jager-Lezer N, Tranchant JF, Alard V, Vu C, Tchoreloff PC, Grossiord JL, Rheol. Acta, 37(2), 129 (1998)
- Kim KY, Lim HJ, Park SM, Lee SJ, Polym.(Korea), 27(4), 377 (2003)
- Lee SJ, Korea-Aust. Rheol. J., 16(3), 153 (2004)
- Nielsen LE, Landel RF, Mechanical Properties of Polymers and Composites, Marcel Dekker, New York, 411-422 (1994)
- Malkin AY, Masalova I, Slatter P, Wilson K, Rheol. Acta, 43(6), 584 (2004)
- Pal R, Colloid Polym. Sci., 277, 583 (1999)
- Pal R, J. Non-Newton. Fluid Mech., 105(1), 21 (2002)
- Princen HM, Kiss AD, J. Colloid Interface Sci., 128, 176 (1989)
- Saiki Y, Prestidge CA, Korea-Aust. Rheol. J., 17(4), 191 (2005)
- Stokes RJ, Evans DF, Fundamentals of Interfacial Engineering, Wiley-VCH, New York, 263-268 (1997)
- Tai H, Sergienko A, Silverstein MS, Polymer, 42(10), 4473 (2001)
- Wakeman RJ, Bhumgara ZG, Akay G, Chem. Eng. J., 70(2), 133 (1998)
- Williams JM, Wrobleski DA, Langmuir, 4, 656 (1988)