페닐 스티릴 케톤 수지의 합성과 이들의 수용액상의 납(II)과 구리(II) 이온의 흡착에의 응용

TashfeenAkhtar; RizwanN.Paracha; ShahidHameed; NasimH.Rama; MasudRiaz; Tashfeen Akhtar; Rizwan N. Paracha; Shahid Hameed; Nasim H. Rama; Masud Riaz

Polymer(Korea), Vol.31, No.2, 93-97, March, 2007

Syntheses of Phenyl Styryl Ketone Resins and Their Applications to the Uptake of Lead(II) and Copper(II) Ions in Aqueous Solutions

TashfeenAkhtar, RizwanN.Paracha, ShahidHameed^†, NasimH.Rama, MasudRiaz¹

Department of Chemistry Quaid-I-Azam University, Islamabad-45320
¹Applied Chemistry Laboratories PINSTECH, P.O. Nilore, Islamabad

Tashfeen Akhtar, Rizwan N. Paracha, Shahid Hameed^†, Nasim H. Rama, and Masud Riaz¹

Department of Chemistry, Quaid-I-Azam University, Islamabad-45320, Pakistan
¹Applied Chemistry Laboratories, PINSTECH, P.O. Nilore, Islamabad, Pakistan

E-mail:

Phenyl styryl ketone ligands 1-5 containing different functional groups were synthesized and attached to the aminated poly(styrene-divinylbenzene) copolymer through diazotization. The coupling of the ligand with polymer was confirmed by FT-IR. The variation of the uptakes of Pb(II) or Cu(II) ions loaded in the prepared polymers (6-10) was examined at different pH values. An increase of metal uptake in the polymers was observed with the increase in pH value in aqueous solution.

Keywords:chelating resins;phenyl styryl ketones;metal ions;uptake

[References]

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[1] Dev K, Rao GN, Talanta, 43, 451 (1996)

[2] Mondal BC, Das AK, React. Funct. Polym., 53, 45 (2002)

[3] Atia AA, Donia AM, Yousif AM, React. Funct. Polym., 56, 75 (2003)

[4] Thamizharasi S, Reddy AVR, Eur. J. Polym., 28, 119 (1992)

[5] Maria LCS, Amorim MCV, Aguiar MRMP, Guimaraes PIC, Costa MAS, Aguiar AP, Rezende PR, Carvalho MS, Barbosa FG, Andrade JM, Ribeiro RCC, React. Funct. Polym., 49, 133 (2001)

[6] Masatoshi K, Toshiro Y, Suzuki TM, Bull. Chem. Soc. Jpn., 62, 3451 (1989)

[7] Degeiso RC, Donaruma LG, Tomic EA, Anal. Chem., 34, 845 (1962)

[8] Jonas PMM, Eve DJ, Parrish JR, Talanta, 36, 1021 (1989)

[9] Furniss BS, Hannaford AJ, Smith PWG, Tatchell AR, "Vogel's Text Book of Practical Organic Chemistry", 5th ed., Longman Scientific and Technical co published with John Wiley and Sons Inc., New York, 1034 (1991)

[10] Ansari FL, Umbreen S, Hussain L, Makhmoor T, Nawaz SA, Lodhi MA, Khan SN, Shaheen F, Choudhary MI, Rahman A, Chem. & Biodiversity, 2, 487 (2005)

[11] Ahmed I, M. Phil Thesis, Department of Chemistry Quaid-i-Azam University, Islamabad, Pakistan (2002)

[12] Samal S, Acharya S, Dey RK, Ray AR, Talanta, 57, 1075 (2002)

[13] Sharma RK, Pure Appl. Chem., 73, 181 (2001)

[14] Davies RA, Kennedy J, Lane ES, Willans JL, J. Appl. Chem., 9, 368 (1959)