Induced pulsing flow (by cyclic liquid feeding) in packed beds, operated in the trickling flow regime, is studied as a method of overall improvement of catalytic reactor operation. In this paper results are reported of experiments aimed at determining local and global liquid/solid mass transfer rates, mainly for the so-called fast mode of ON-OFF periodic liquid feeding, with frequencies of order 0.1 Hz. Such mass transfer data for the fast mode of induced pulsing are not available in the literature. Uniform 6 mm glass spheres and alumina cylindrical extrudates, of 1.5 mm diameter and a narrow distribution of lengths, are employed in the tests. For completeness, results are also reported for single-phase (liquid) and trickling flow through the same packed beds. A well-known electrochemical technique is employed to measure instantaneous local mass transfer coefficients by means of quite a few probes distributed throughout the bed. The hydrodynamic characteristics under the above conditions, reported in companion papers, are helpful in interpreting the new mass transfer data. There is a wide spread of the time-averaged local mass transfer rates, in all cases tested, apparently due to packing and flow non-uniformities. This spread is much smaller in the case of packed uniform spheres. In general, the benefits of cyclic liquid feeding are more evident in the packed bed of spheres than in that of cylindrical extrudates; for instance, with increasing mean liquid rate, induced pulsing tends to reduce the spread of local mass transfer coefficients, which suggests that more uniform fluids distribution is promoted. The imposed liquid pulses are reflected in the observed periodic variation of local mass transfer coefficients; the latter appear to decay along the bed in the same manner as the liquid pulses. Other trends of local mass transfer rates are identified and discussed in relation to measured variation of liquid holdup, under the same conditions. For packed spheres, the measured global mass transfer rates are in fair agreement with literature correlations obtained for the trickling flow regime, unlike the case of packed extrudates where significant deviation is observed. (c) 2006 Elsevier Ltd. All rights reserved.