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Chemical Reviews, Vol.99, No.3, 881-930, 1999
Progress in the construction of cyclooctanoid systems: New approaches and applications to natural product syntheses
Keywords:DIELS-ALDER REACTION;RADICAL RING EXPANSION;OXY-COPEREARRANGEMENT;HIGHER-ORDER CYCLOADDITION;1ST TOTAL SYNTHESIS;8-MEMBERED B-RING;NI(II)/CR(II)-MEDIATED COUPLING REACTION;INTRAMOLECULAR 4+3 CYCLOADDITIONS;TRANSANNULAR CYCLIZATIONSTRATEGY;PALLADIUM-CATALYZED CYCLIZATIONS