The purpose of this study is to determine the thermal reliability and corrosion of the Al-34%Mg-6%Zn alloy as a latent heat energy storage material with respect to various numbers of thermal cycles. The differential scanning calorimeter (DSC) analysis technique was applied to the alloy after 0, 50, 500 and 1000 melting/solidification cycles in order to measure the melting temperatures and the latent heats of fusion of the alloy. The containment materials were stainless steel (SS304L), carbon steel (steel C20) in the corrosion tests. The DSC results indicated that the change in melting temperature for the alloy was in the range of 3.06-5.3 K, and the latent heat of fusion decreased 10.98% after 1000 thermal cycles. The results show that the investigated Al-34%Mg-6%Zn alloy has a good thermal reliability as a latent heat energy storage material with respect to thermal cycling for thermal energy storage applications in the long term in view of the small changes in the latent heat of fusion and melting temperature. Gravimetric analysis as mass loss (mg/cm(2)), corrosion rate (mg/day) and a microscopic or metallographic investigation were performed for corrosion tests and showed that SS304L may be considered a more suitable alloy than C20 in long term thermal storage applications. (c) 2006 Elsevier Ltd. All rights reserved.