화학공학소재연구정보센터
Industrial & Engineering Chemistry Research, Vol.46, No.5, 1485-1491, 2007
Dynamics of transversal hot zones in a shallow packed bed reactor during oxidation of mixtures of C3H6 and CO
The evolution and motions of transversal hot zones on the top of a shallow packed bed reactor, in which the atmospheric oxidation of either propylene or its mixture with CO took place, were studied using infrared thermography. The hot regions were separated by a sharp temperature front from the adjacent colder region (Delta T similar to 50 degrees C). The period of the oscillations of mixtures of propylene and carbon monoxide was about 20 times shorter than those of CO and about 2 times shorter than those of propylene. This indicates that the frequency of the hot zone motions is affected mainly by the kinetics of the catalytic reaction and the strength of adsorption of the organic reactants and not by the properties of the bed and/or the flow through it. The mixture of the two reactants led to the formation of a moving hot spot over a much wider range than that of either reaction, and under operating conditions for which neither one of the two reactions led to formation of hot regions. The experiments seem to confirm the prediction by Viswanathan and Luss (Viswanathan, G. A.; Luss, D. AIChE. J. 2006, 52, 705-717), that transversal hot zones are likely to form in a shallow packed bed reactor for reactions whose rates may exhibit oscillatory behavior.