화학공학소재연구정보센터
Industrial & Engineering Chemistry Research, Vol.46, No.5, 1578-1583, 2007
Kinetics of CO2 absorption in aqueous sodium glycinate solutions
The physical solubility and diffusivity of N2O and CO2 in aqueous sodium glycinate (SG) solutions of various concentrations (1.0-3.5 kmol/m(3)) and temperatures (303.15-323.15 K) were reported. The kinetics of the reaction between CO2 and SG has been studied using absorption data measured by a wetted-wall column apparatus at various temperatures and concentrations. The second-order rate constant of CO2 with SG was determined to be k(2)(m(3) kmol(-1) s(-1)) = 1.95 x 10(13) exp(-7670/T), where T is the absolute temperature (given in Kelvin). The activation energy for the reaction of CO2 with SG was calculated to be 63.8 kJ/mol.