Mesoporous silica materials have been prepared using aqueous solutions of hydrogenated-fluorinated surfactant mixtures. The phase behavior of the C18H35(OC2H4)(10)-C6F15C2H4(OC2H4)(11)OH [R-18(H)(EO)(10)-R-6(F)(EO)(11)] mixture in aqueous solution was first established at the temperature at which the silica source is added, i.e., 20 or 40 degrees C. We have delimited the different phase domains. Concerning the mesostructured silica, whatever the temperature at which the silica source is added, mesoporous material with a hexagonal array of their channel is formed via a cooperative templating mechanism (CTM), if the content of R-6(F)(EO)(11) in the surfactant mixture is lower than 50%. Moreover, when the silica source is added at 40 degrees C, the recovered materials exhibit a bimodal pore size distribution. The appearance of this bimodality has been related to the coexistence of hydrogenated micelles with fluorinated wormlike micelles. By contrast, the bimodality is not observed when the silica source is added at 20 degrees C.