4차 암모늄 염을 포함하는 폴리메타크릴레이트 습도센서

홍채환; 김세훈; 남병욱; Chae-Hwan Hong; Se-Hoon Kim; Byeong-Uk Nam

Polymer(Korea), Vol.31, No.3, 255-262, May, 2007

Export Citation

4차 암모늄 염을 포함하는 폴리메타크릴레이트 습도센서

Humidity Sensor of Polymethacrylate with 4th Ammonium Salt

홍채환, 김세훈¹, 남병욱^{2, †}

현대자동차 연구개발본부 고분자재료연구팀
¹K-Won 전자
²한국기술교육대학교 응용화학공학과

Chae-Hwan Hong, Se-Hoon Kim¹, and Byeong-Uk Nam^{2, †}

Hyundai-Kia Motors Co., Ltd., 772-1, Jangduk-dong, Hwaseong-cityi, Gyeonggi-Do 445-855, Korea
¹K-Won Electronic, Baesuk-dong, Cheonan, Chungnam, Korea
²Department of Chemical Engineering, Korea University of Technology Education, Cheonan 333-860, Korea

E-mail:

초록

고분자 습도센서 막으로 사용하기 위한 두 가지 타입의 공중합체를 라디칼 중합방식에 의하여 제조하였다. 각각 공중합체는 세 가지의 단량체를 포함하여 제조하였는데, 각 단량체들은 습도 저항성, 막 안정성, 유연성, 임피던스 및 전극 부착력을 증대시키는 효과를 가지도록 하였다. 염 형태의 MDBAB는 제조된 습도 막의 임피던스를 감소시키는 효과를 보였으며 아민과 반응하여 가교 구조를 생성하였다. DAEMA, 4-VP, 및 2-EHA를 사용하여 습도막 제조를 위하여 몇 가지 조성물을 제조하였다. 특정 조성 조건에서 성능 및 장기 내구성 측면에서 우수한 결과를 얻을 수 있었다.

In this work, two types of copolymers are manufactured by a radical polymerization to develop a material for humid membrane. Each copolymer contains three monomers that have functions to improve humid-resistance, membrane stability, flexibility, impedance, and adhesion to the electrode. MDBAB(N,N -dimethyl-2-methacryloxyethyl-3-bromopropyl ammonium bromide) having a salt form decreases the impedance of the humid membrane and reacts with amines to produce a cross-linking structure. HEMA (2-hydroxyethyl methacrylate) has an important role which reduces the impedance and increases the adhesion strength to the electrode. The other monomers are DAEMA(N,N-dimethylamino ethyl methacrylate), 4-VP(4-vinyl pyridine), and 2-EHA(2-ethylhexyl acrylate) and all the monomers are formulated with several compositions to make a humid membrane. At specific composition, we could attain a satisfactory results having good performance and long term durability.

Keywords:humidity sensor;radical polymerization;membrane

[References]

Seiyma T, Yamazoe N, Arai H, Sens. Actuators B-Chem., 4, 85 (1983)
Katayama K, Hasegawa K, Takahashi Y, Akiba T, Sens. Actuators B-Chem., 24, 55 (1990)
Shimizu Y, Arai H, Seiyama T, Sens. Actuators B-Chem., 7, 11 (1985)
Yokomizo Y, Uno S, Harata M, Hirak H, Sens. Actuators B-Chem., 4, 599 (1983)
Sakai Y, Sadaoka Y, Ikeuchi K, Sens. Actuators B-Chem., 9, 125 (1986)
Hijikigawa M, Miyosh S, Sugihara T, Jinda A, Sens. Actuators B-Chem., 4, 307 (1983)
Jo JS, Gong MS, Lee HM, Kim, Lee IY, Polymer, 16, 16 (1992)
Otsuki S, Dozen Y, Jpn. J. Polym. Sci. Tech., 45, 549 (1988)
Sakai Y, Sadaoka Y, Ikeuchi K, Sens. Actuators B-Chem., 16, 359 (1989)
Sakai Y, Sadaoka Y, Ilukumoto, Sens. Actuators B-Chem., 13, 243 (1988)
Sakai Y, Sadaoka Y, Matsuguchi M, Handbook of Materials and Moisture, Measurements in Polymer Science, Kyoritsu Publish, p.151 (1990)
Zilig C, Mulhaupt R, Finter J, Macromol. Chem. Phys., 200, 661 (1999)
Hsiao SH, Liou GS, Chang LM, J. Appl. Polym. Sci., 80(11), 2067 (2001)
Agag T, Koga T, Takeichi T, Polymer, 42(8), 3399 (2001)
Wang J, Do J, Zhu J, Wilkie CA, Polym. Degrad. Stabil., 77, 249 (2002)

[1] Seiyma T, Yamazoe N, Arai H, Sens. Actuators B-Chem., 4, 85 (1983)

[2] Katayama K, Hasegawa K, Takahashi Y, Akiba T, Sens. Actuators B-Chem., 24, 55 (1990)

[3] Shimizu Y, Arai H, Seiyama T, Sens. Actuators B-Chem., 7, 11 (1985)

[4] Yokomizo Y, Uno S, Harata M, Hirak H, Sens. Actuators B-Chem., 4, 599 (1983)

[5] Sakai Y, Sadaoka Y, Ikeuchi K, Sens. Actuators B-Chem., 9, 125 (1986)

[6] Hijikigawa M, Miyosh S, Sugihara T, Jinda A, Sens. Actuators B-Chem., 4, 307 (1983)

[7] Jo JS, Gong MS, Lee HM, Kim, Lee IY, Polymer, 16, 16 (1992)

[8] Otsuki S, Dozen Y, Jpn. J. Polym. Sci. Tech., 45, 549 (1988)

[9] Sakai Y, Sadaoka Y, Ikeuchi K, Sens. Actuators B-Chem., 16, 359 (1989)

[10] Sakai Y, Sadaoka Y, Ilukumoto, Sens. Actuators B-Chem., 13, 243 (1988)

[11] Sakai Y, Sadaoka Y, Matsuguchi M, Handbook of Materials and Moisture, Measurements in Polymer Science, Kyoritsu Publish, p.151 (1990)

[12] Zilig C, Mulhaupt R, Finter J, Macromol. Chem. Phys., 200, 661 (1999)

[13] Hsiao SH, Liou GS, Chang LM, J. Appl. Polym. Sci., 80(11), 2067 (2001)

[14] Agag T, Koga T, Takeichi T, Polymer, 42(8), 3399 (2001)

[15] Wang J, Do J, Zhu J, Wilkie CA, Polym. Degrad. Stabil., 77, 249 (2002)