화학공학소재연구정보센터
Journal of Chemical Thermodynamics, Vol.39, No.2, 225-229, 2007
Saturated liquid densities of propane at T = (280 to 365) K
Saturated liquid densities for propane were obtained by means of a metal-bellows variable volumometer at T = (2 80, 300, 320, 340, 360, and 365) K. The mol-fraction purity of the propane used in the measurements was 0.99997. The expanded uncertainties (k = 2) in temperature, pressure, and density measurements were estimated to be less than +/- 3 mK, 1.4 kPa (p <= 7 MPa), and +/- 0.09%, respectively. For the determination of the saturation boundary at each temperature for propane, we measured the density data at intervals of about 20 kPa very close to the saturation boundary. After such measurements had been completed, the saturated liquid density data at each temperature were determined as the intersection between the isotherm and our previously determined vapour pressure value. The discrepancies between the three series in the present measurements, in which different sample fillings were used, were also confirmed to be sufficiently lower than the experimental uncertainty. The saturated liquid density correlation was also provided for the systematic comparisons between the present measurements and the literature data. (c) 2006 Elsevier Ltd. All rights reserved.