Journal of the American Chemical Society, Vol.129, No.12, 3496-3496, 2007
Reversible water-induced magnetic and structural conversion of a flexible microporous Ni(II)Fe(III) ferromagnet
A cyanide-bridged bimetallic ferromagnet, [Ni(dipn)](2)[Ni(dipn)(H2O)][Fe(CN)(6)](2)center dot 11H(2)O (dipn = N,N-di(3-aminopropyl)amine) providing a 3-D microporous framework, shows reversible ferromagnet/paramagnet conversion associated with a gaseous water-induced crystal-to-amorphous-like phase transformation.