Contact angle behavior of four relatively high surface tension ionic liquids (1,3-dimethylimidazolium methyl sulfate, 1-ethyl-3-methylimidazolium ethyl sulfate, 1-ethyl-3-methylimidazolium fluoroborate, and bis(hydroxyethyl)dimethylammonium methane sulfonate) was studied on seven hydrophobic surfaces and compared with water contact angle behavior. Smooth surfaces of various chemical compositions exhibit contact angles with ionic liquids that are lower than values obtained with water and that scale with liquid surface tension values. Contact angles of ionic liquids on rough perfluoroalkyl surfaces exhibit the highest contact angles reported for liquids other than water and are indistinguishable from those of water and not dependent on liquid surface tension. Superhydrophobic methylsilicone surfaces that exhibit high water contact angles and low hysteresis exhibit very low receding contact angles with ionic liquid probe fluids and high hysteresis. The potential for ionic liquids as probe fluids is argued because of their variable and controllable surface tension, interface charge density, interface dipole density, as well as their variable and controllable cation/anion structure and molecular volume.