화학공학소재연구정보센터
Journal of Power Sources, Vol.166, No.1, 47-52, 2007
Synthesis and properties of Y-doped SrTiO3 as an anode material for SOFCs
Y-doped SrTiO3 was synthesized via solid-state reaction. The effects of Y-doping on the sinterability and the electrical conductivity of YxSr1-xTiO3 were investigated. Y-doping can increase the sintering activity and the electrical conductivity of SrTiO3 when yttrium amount is less than 0.09 in YxSr1-xTiO3. Excessive yttriurn will cause the generation of an insulating phase Y2Ti2O7, Which impedes the densification process and decreases the electrical conductivity of YxSr1-xTiO3 material. With the increased temperature, the electrical conductivity of Y-doped SrTiO3 increases first and then decreases gradually, showing a mixed conduction behavior of semi-conductors and metals. The optimized Y0.09Sr0.91TiO3 possesses an electrical conductivity on the order of 32.5-195.8 S cm(-1) in the temperature range of 25-1000 degrees C and being 73.7 S cm(-1) at 800 degrees C in forming gas. The thermal cycling in air does not remarkably affect the electrical conductivity and the conduction behavior of Y0.09Sr0.91TiO3 at high temperatures. Y0.09Sr0.91TiO3 displays a relatively stable electrical conductivity at different oxygen partial pressures and excellent chemical compatibility with YSZ at temperatures lower than 1300 degrees C. (c) 2007 Elsevier B.V. All rights reserved.