Chemical Physics Letters, Vol.325, No.1-3, 73-78, 2000
Quantum wave packet dynamics with trajectories: reflections on a downhill ramp potential
The quantum trajectory method (QTM) for wave packet dynamics involves solving discretized hydrodynamic equations-of-motion in the Lagrangian picture (C. Lopreore, R.E. Wyatt, Phys. Rev. Leu. 82 (1999) 5190). In this Letter, results are presented which illustrate the dynamics of an initial Gaussian wave packet on a downhill ramp potential. Plots are shown for the time evolving probability density, as well as phase space plots and force diagrams. The mechanism, deduced from these plots, surprisingly shows some of the transmitted fluid elements of the wave packet making a U-turn before they head downhill on the ramp potential.