Chemical Physics Letters, Vol.326, No.3-4, 277-282, 2000
Unexpected stability of vinylidene from 5D ab initio quantum-dynamical calculations
We report results of 5D quantum-dynamical simulations for the vibrational levels and lifetime of vinylidene. The calculations are based on a new ab initio potential energy surface and reproduce the observed vibrational structure of the photodetachment spectrum very well. The lifetimes thus obtained exceed previous estimates in the literature by 2-3 orders of magnitude.